94) Ragunathan, G.; Mishra, S.; Zhang, X.; Schmehl, R. H.; Mague, J. T.; Donahue, J. P. Small Molecules Models of H2-Evolving MS2 (M = Mo, W) Bulk Solids: Composition-Activity Relationships. ACS Catalysis, Manuscript in Preparation.

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93) Fraker, A.; Donahue, J. P.; McSkimming, A. J. Bis[tris(di-isobutyldithiocarbamato)-tris(μ2-disulfido)-(μ3-sulfido)-trimolybdenum(IV)]2(μ6-S) THF Solvate. Acta Crystallogr., Sect. E 2024, Submitted.

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92) Ragunathan, G.; Mishra, S.; Mague, J. T.; Zhang, X.; Donahue, J. P. Probing the Limits of Tetraalkylthiuram Disulfide Synthesis by Direct Reaction of Secondary Amines with CS2: Cy2NC(S)SSC(S)NCy2 and Cy2NC(S)SSSSC(S)NCy2. Phosphorus, Sulfur Silicon Relat. Elem. 2024, Submitted.

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 91) Zhang, X.; Donahue, J. P. Using Partial Structure R1 Factor to Do Molecular Replacement Calculations. Acta Crystallogr., Sect. A 2023, Accepted.

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 90) Wu, C.; Kakarla, L. N.; Chandrasekaran, C. P.; Zhang, X.; Mague, J. T.; Sproules, S.; Donahue, J. P. Asymmetric by Design: Heteroleptic Coordination Compounds with Redox-Active Dithiolene and 1,2,4,5-Tetrakis(isopropylthio)benzene Ligands. Inorg. Chem. 2023, 62. DOI: 10.1021/acs.inorgchem.3c02928.

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 89) Wang, B.; Barnes, J.; Ferrara, S. J.; Sproules, S.; Zhang, X,; Mague, J. T.; Donahue, J. P. Fully Reduced and Mixed-Valent Multi-Copper Aggregates Supported by Tetradentate Diamino Bis(thiolate) Ligands. Inorg. Chem. 2023, 62, 9854-9871. DOI: 10.1021/acs.inorgchem.3c00784.

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88) Das Gupta, T.; Applebaum, J.; Broussard, W.; Mack, C. Wu, C.; Mague, J. T.; Donahue, J. P. Bis[1,2-bis(4-tert-butylphenyl)ethylene-1,2-dithiolato(1–)]nickel(II). Acta Crystallogr., Sect. E 2023, 79, 182-186. DOI: 10.1107/S205698902300097X.

 

87) Kumar, S.; Selvachandran, M.; Wu, C.; Pascal, R. A., Jr.; Zhang, X.; Grusenmeyer, T.; Schmehl, R. H.; Sproules, S.; Mague, J. T.; Donahue, J. P. Heterotrimetallic Assemblies with 1,2,4,5-Tetrakis(diphenylphosphino)benzene Bridges: Constructs for Controlling the Separation and Spatial Orientation of Dithiolene-Based Electron Spins. Inorg. Chem. 2022, 61, 17804-17818. DOI: 10.1021/acs.inorgchem.2c03112.

 

86) Chandrasekaran, C. P.; Donahue, J. P. Crystal Structure of 4,5-Dimethyl-1,3-dioxol-2-one. Acta Crystallogr., Sect. E 2022, 78, 1-4. DOI: 10.1107/S2056989022009239.

 

85) Koehne, S.; Mirmelli, B.; Mague, J. T.; Donahue, J. P. Bis[1,2-di(p-chlorophenyl)-1,2-ethylenedithiolato]nickel. IUCr Data Reports 2022, 7, x220148. DOI: 10.1107/S2414314622001481.

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84) Balch, A.; Everett, G.; Power, P. P.; Armstrong, W. H.; Kovacs, J.; Stack, T. D. P.; Donahue, J. P.; Gray, T. G.; Groysman, S.; Deng, L. Richard Hadley Holm: A Remembrance and a Tribute. Comments Inorg. Chem. 2021, 41, Accepted.

 

83) Kumar, S.; Selvachandran, M.; Arumugam, K.; Shaw, M. C.; Wu, C.; Maurer, M.; Zhang, X.; Sproules, S.; Mague, J. T.; Donahue, J. P. Open-Ended Metallodithiolene Complexes with the 1,2,4,5-Tetrakis(diphenylphosphino)benzene (tpbz) Ligand: Modular Building Elements for the Synthesis of Multimetal Complexes. Inorg. Chem. 2021, 60, In press. DOI: 10.1021/acs.inorgchem.1c01573.

 

82) Selvachandran, M.; Kumar, S.; Zhang, X.; Mague, J. T.; Donahue, J. P. Tetrakis-1,2,4,5-(bis(3,5-dimethylphenyl)-phosphino)benzene (Me16tpbz): A Soluble and Spectroscopically  Simple Variant of the 1,2,4,5-Tetraphosphinobenzene Ligand Platform. Polyhedron 2021, 196, 114985. DOI: 10.1016/j.poly.2020.114985.

 

81) Maier, S.; Donahue, J. P.; Jacobsen, H. Surprises with Coordination Geometries of Cationic Copper(I) Complexes. Polyhedron2021, 194, 114941. DOI: 10.1016/j.poly.2020.114941.

 

80) Obanda, A.; Valerius, K.; Sproules. S.; Mague, J. T. Group 10 Metal Dithiolene Bis(isonitrile) Complexes: Synthesis, Structures, Properties and Reactivity. Organometallics 2020, 39, 2854-2870. DOI: 10.1021/acs.organomet.0c00375.

 

79) Chen, Y.; Wang, B.; Fontenot, P.; Donahue, J. P. Tris[N,N-bis(3,5-di-tert-butylbenzyl)dithiocarbamato-κ2S,S']-μ3-sulfido-tris-μ2-disulfido-triangulo-trimolybdenum(IV) iodide. IUCrData 2020, 5, x200939. DOI: 10.1107/S2414314620009396.

 

78) Brakefield, K.; Barnes, J. B. Donahue, J. P. The Crystal Structure of [Mo3Se7(S2CNEt2)3)]2(μ-Se) Bis(1,2-dichlorobenzene) Solvate. Z. Kristallogr. 2020, 235, 739-743. DOI: 10.1515/ncrs-2019-0938.

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77) Fontenot, P. R.; Shan, B.; Wang, B.; Simpson, S.; Ragunathan, G.; Greene, A. F.; Obanda, A.; Hunt, L. A.; Hammer, N. I.; Webster, C. E.; Mague, J. T.; Schmehl, R. H.; Donahue, J. P. "Photocataltyic H2-Evolution by Homogeneous Molybdenum Clusters Supported by Dithiocarbamate Ligands " Inorg. Chem. 2019, Submitted.

 

76) Dougherty, K. J.; Qin, Q.; Cruz, R.; Cho, Y.; Donahue, J. P.; Mague, J. T.; Pascal, R. A., Jr. A Simple Serendipitous Synthesis of Heterohexahelicenes. Eur. J. Org. Chem. 2019, Accepted.

 

75) Spring, S.; Shinde, P. S.; Fontenot, P. R.; Donahue, J. P.; Pan, S. Self-Assembled Monolayers of Molybdenum Sulfide Clusters on Au Electrode as Hydrogen Evolution Catalyst for Water Splitting. Inorganics 2019, 7(6), 79. DOI: 10.3390/inorganics7060079.

 

74) Maguire, J.; Miras, H. H.; Donahue, J. P.; Richards, E.; Sproules, S. "Ligand Radicals as Modular Organic Electron Spin Qubits." Chem. Eur. J. 2018, 24, 17598-17605. DOI: 10.1002/chem.201804165.

 

73) Goyal, N.; Donahue, J. P.; Do, C.; Perry, T.; Bongay-Williams, K.; Foroozesh, M. "A Dibenzofuran Derivative: 2-(Pentyloxy)dibenzo[b,d]furan." IUCrData 2018, 3, x181306. DOI: 10.1107/S2414314618013068.

 

72) Goyal, N.; Do, C.; Donahue, J. P.; Mague, J. T.; Foroozesh, M. "Ethyl 2-[2-(4-oxo-4H-chromen-2-yl)phenoxy]-acetate." IUCrData 2018, 3, x180993. DOI: 10.1107/S2414314618009938.

 

71) Shinde, P. S.; Fontenot, P.; Donahue, J. P.; Waters, J. L.; Kung, P.; McNamara, L. E.; Hammer, N. I.; Gupta, A.; Pan, S. "Synthesis of MoS2 from [Mo3S7(S2CNEt2)3]I for Enhancing Photoelectrochemical Performance and Stability of Cu2O Photocathode Toward Efficient Solar Water Splitting." J. Mat. Chem A. 2018, 6, 9569-9582. DOI: 10.1039/C8TA01771A.

 

70) Arumugam, K.; Selvachandran, M.; Obanda, A.; Shaw, M. C.; Chandrasekaran, P.; Caston Good, S. L.; Mague, J. T.; Sproules, S.; Donahue, J. P. "Redox-Active Metallodithiolene Groups Separated by Insulating Tetraphosphinobenzene Spacers." Inorg. Chem. 2018, 57, 4023-4038. DOI: 10.1021/acs.inorgchem.8b00201.

 

69) Fontenot, P.; Wang. B.; Chen, Y.; Donahue, J. P. "Crystal Structure of Tetraisobutylthiuram Disulfide." Acta Crystallogr., Sect. E 2017, 73, 1764-1769. DOI: 10.1107/S2056989017015158.

 

68) Obanda, A.; Martinez, K.; Schmehl, R. H.; Mague, J. T.; Rubtsov, I. V.; MacMillan, S. N.; Lancaster, K. M.; Sproules, S.; Donahue, J. P. "Expanding the Scope of Ligand Substitution from [(Ph2C2S2)2M] (M = Ni2+, Pd2+, Pt2+) to Afford New Heteroleptic Dithiolene Complexes." Inorg. Chem. 2017, 56, 10257-10267, DOI: 10.1021/acs.inorgchem.7b00971.

 

67) Ferrara, S. J.; Wang. B.; Haas, E.; Wright LeBlanc, K.; Mague, J. T.; Donahue, J. P. "Synthesis and Structures of [LCu(I)(SSiiPr3)] (L = triphos, carbene) and Related Compounds." Inorg. Chem. 2016, 55, 9173-9177. DOI: 10.1021/acs.inorgchem.5b02811.

 

66) Sullivan M. R.; Sokkalingam, P.; Nguyen, T.; Donahue, J. P.; Gibb, B. C. "Binding of Carboxylate and Trimethylammonium Salts to Octa-acid and TEMOA Deep Cavity Cavitands." J. Computer-Aided Mol. Des. 2016, In Press. DOI: 10.1007/s10822-016-9925-0.

 

65) Geng, X.; Mague, J. T.; Donahue, J. P.; Pascal, R. A. "Hairpin Furans and Giant Biaryls." J. Org. Chem. 2016, 81, 3838-3847. DOI: 10.1002/anie.201506792.

 

64) Ferrara, S. J.; Wang, B.; Donahue, J. P. "An S4-Symmetric Mixed-Valent Decacopper Cage Comprised of [CuII(L-S2N2)] Complexes Bridged by CuI(MeCN)n (n = 1 or 2) Cations." Dalton Trans. 2016, 45, 2997-3002. DOI: 10.1039/C5DT04359J.

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63) Geng, X.; Donahue, J. P.; Mague, J. T.; Pascal, Jr., R. A. "The Hairpin Furans: Easily Prepared Hybrids of Helicenes and Twisted Acenes." Angew. Chem. Int. Ed. 2015, 54, 13957-13960. DOI: 10.1002/anie.201506792.

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62) Pingali. S.; Donahue, J. P.; Payton-Stewart, F. ʺTetrahydroberberine, A Pharmacologically Active Naturally Occurring Alkaloid.ʺ Acta Crystallogr., Sect. C 2015, 71, 262-265. DOI: 10.1107/S2053229615004076.

 

61) Yan, Y.; Mague, J. T.; Donahue, J. P.; Sproules, S. ʺUnprecendented Spin Localisation in a Metal-Metal Bonded Dirhenium Complex.ʺ Chem. Commun. 2015, 51, 5482-5485. DOI: 10.1039/c4cc09397f.

 

60) Chandrasekaran, P.; Greene, A. F.; Lillich, K.; Capone, S.; Mague, J. T.; DeBeer, S.; Donahue, J. P. ″A Structural and Spectroscopic Investigation of Octahedral Platinum Bis(dithiolene) Phosphine Complexes: Phosphine Association Enabled by Platinum-Dithiolene Internal Redox Chemistry.″ Inorg. Chem. 2014, 53, 9192-9205. DOI: 10.1021/ic501273b.

 

59) Jayarathne, U.; Chandrasekaran; P. Greene, A. F.; Mague, J. T.; DeBeer, S.; Lancaster, K. M.; Sproules, S.; Donahue, J. P. ″X-ray Absorption Spectroscopy Systematics at the Tungsten L-Edge.″ Inorg. Chem. 2014, 53, 8230-8241. DOI: 10.1021/ic500256a.

 

58) Pingali, S.; Donahue, J. P.; Payton-Stewart, F. ″Weak C−H→X (X = O, N) Hydrogen Bonds in the Crystal Structure of Dihydroberberine.″ Acta Crystallogr., Sect. C 2014, 70, 388-391. DOI:10.1107/S2053229614003751.

 

57) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. "Supramolecular Arrays Based on Dimolybdenum Building Blocks." Inorg. Synth. 2014, 36, 82-95. DOI: 10.1002/9781118744994.ch17.

 

56) Greene, A. F.; Chandrasekaran, P.; Yan, Y.; Mague, J. T.; Donahue, J. P. ″Element Misidentification in X-ray Crystallography: A Reassessment of the [MCl2(diazadiene)] (M = Cr, Mo, W) Series.″ Inorg. Chem. 2014, 53, 308-317. DOI: 10.1021/ic402246d.

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55) Yue, Y.; Grusenmeyer, T.; Ma, Z.; Zhang, P.; Pham, T. T.; Mague, J. T.; Donahue, J. P.; Schmehl, R. H.; Beratan, D. N.; Rubtsov, I. V. ″Evaluating the Extent of Intramolecular Charge Transfer in the Excited States of Rhenum(I) Donor−Acceptor Complexes with Time-Resolved Vibrational Spectroscopy. ″ J. Phys. Chem. B 2013, 117, 15903-15916. DOI: 10.1021/jp409628e

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54) Yan, Y.; Keating, C.; Chandrasekaran, P.; Jayarathne, U.; Mague, J. T.; DeBeer, S.; Lancaster, K. M.; Sproules, S.; Rubtsov, I. V.; Donahue, J. P. ″Ancillary Ligand Effects upon Dithiolene Redox Noninnocence in Tungsten Bis(dithiolene) Complexes.″ Inorg. Chem. 2013, 52, 6743-6751. DOI: 10.1021/ic4009174

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53) Payton-Stewart, F.; Pingali, S. R. K.; Donahue, J. P. ″ The chalcone derivative (E)-1-(4-fluorophenyl)-3-(4-hydroxy-3-methoxyphenyl)prop-2-en-1-one monohydrate.″ Acta Crystallogr., Sect. E. 2013, 69, o558-o559. DOI:10.1107/S160053681300696X

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52) Jayarathne, U.; Mague, J. T.; Donahue, J. P. ″Hexamethylphosphorus Triamide: A Chloride-for-Dimethylamido, Me2N-, Exchange Reagent.″ Polyhedron 2013, 58, 13-17. DOI:10.1016/j.poly.2012.08.031

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51) Ferrara, S. J.; Mague, J. T.; Donahue, J. P. ″Synthesis and Structures of Cuprous Triptycylthiolate Complexes.″ Inorg. Chem. 2012, 51, 6567-6576. DOI: 10.1021/ic300124n

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50) Yan, Y.; Chandrasekaran, P.; Mague, J. T.; DeBeer, S.; Sproules, S.; Donahue, J. P. "Redox-Controlled Interconversion between Trigonal Prismatic and Octahedral Geometries in a Monodithiolene Tetracarbonyl Complex of Tungsten." Inorg. Chem. 2012, 51, 346-361. DOI: 10.1021/ic201748v

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49) Jayarathne, U.; Williams, K.; Kasyanenko, V.; Mague, J. T.; Rubtsov, I. V.; Donahue, J. P. ″Structural Characterization of [Fe(NO)(mnt)2]1-/2- Salts.″ Polyhedron 2012, 31, 98-103. DOI:10.1016/j.poly.2011.09.001

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48) Arumugam, K.; Clark, D. S.; Mague, J. T.; Donahue, J. P. ″The Dithiolene Ligand and Tetrathiafulvulvalene Precursor Molecules 4,5-Di(bromomethyl)-1,3-dithiol-2-one and 4,5-Di(methylphosphonic acid)-1,3-dithiol-2-one.″ Acta Crystallogr., Sect. C. 2011, 67, o446-o449. DOI: 10.1107/S0108270111040431

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47) Sproules, S.; Banerjee, P.; Weyhermüller, T.; Yan, Y.; Donahue, J. P.; Wieghardt, K. ″Monoanionic Molybdenum and Tungsten Tris(dithiolene) Complexes: A Multifrequency Study.″ Inorg. Chem. 2011, 50, 7106-7122. DOI: 10.1021/ic2006265

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46) Arumugam, K.; Shaw, M. C.; Mague, J. T.; Bill, E.; Sproules, S.; Donahue, J. P. "Long Range Spin Coupling: A Tetraphosphine-Bridged Palladium Dithiolene Dimer." Inorg. Chem. 2011, 50, 2995-3002. DOI: 10.1021/ic102493g

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45) Ferrara, S. J.; Mague, J. T.; Donahue, J. P. "trans-Bis(N,N-diethylenediamine)-nickel(II) Dibromide." Acta Crystallogr, Sect. E 2011, 67, m48-m49. DOI:10.1107/S1600536810050403

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44) Jayarathne, U.; Chandrasekaran, P.; Jacobsen, H.; Mague, J. T.; Donahue, J. P. "A Tungsten-Mediated Closed Cycle of Reactivity for the Reduction of CO2 to CO." J. Chem. Soc., Dalton Trans. 2010, 9662-9671. DOI: 10.1039/c0dt00489h

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43) Kuang, X.-F.; Yu, R.; Wu, X.-Y.; Donahue, J. P.; Huang, J.-S.; Lu, C.-Z. "Assembly of a Metal-Organic Framework by Sextuple Intercatenation of Discrete Adamantane-Like Nanocages." Nature Chemistry 2010, 2, 461-465. DOI:10.1038/nchem.618

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42) Medina Ramírez, I. E.; Fink, M. J.; Donahue, J. P. "Tetrakis(μ-triisopropylsilanethiolato)-1:2κ4S:S;2:3κ4S:S-bis(triisopropylsilanethiolato)-1κS,3κS-trizinc(II)." Acta Crystallogr, Sect. C. 2009, C65, m475-m477. DOI:10.1107/S0108270109045570

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41) Yu, R.; Kuang, X.-F.; Wu, X.-Y.; Lu, C.-Z.; Donahue, J. P. "Stabilization and Immobilization of Polyoxometalates in Porous Coordination Polymers through Host-Guest Interactions." Coord. Chem. Rev. 2009, 253, 2872-2890. DOI:10.1016/j.ccr.2009.07.003

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40) Arumugam, K.; Shaw, M. C.; Chandrasekaran, P.; Villagrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P.  "Synthesis, Structures and Properties of 1,2,4,5-Benzenetetrathiolate Linked Group 10 Metal Complexes. Inorg. Chem. 2009, 48, 10591-10607. DOI: 10.1021/ic901257s

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39) Kasyanenko, V. M.; Lin, Z.; Rubtsov, G. I.; Donahue, J. P.; Rubtsov, I. V. "Energy Transport via Coordination Bonds." J. Chem. Phys. 2009, 131, 154508-1 – 154508-12. DOI: org/10.1063/1.3246862

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38) Chandrasekaran, P.; Donahue, J. P. "Synthesis of 4,5-Dimethyl-1,3-dithiol-2-one." Org. Synth. 2009, 86, 333-343. DOI: 10.1002/0471264229.os086.32

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37) Yan, Y.; Mague, J. T.; Donahue, J. P. "A Polymorph of Tetraethylammonium Chloride." Acta Crystallogr, Sect. E 2009, 65, o1491. DOI:10.1107/S160053680902042X

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36) Chandrasekaran, P.; Arumugam, K.; Jayarathne, U.; Pérez, L.; Mague, J. T.; Donahue, J. P. "Synthesis, Structures and Properties of Mixed Dithiolene-Carbonyl and Dithiolene-Phosphine Complexes of Tungsten." Inorg. Chem. 2009, 48, 2103-2113. DOI: 10.1021/ic802016b

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35) Jacobsen, H.; Donahue, J. P. "Computational Study of Iron Bis(dithiolene) Complexes: Redox Noninnocent Ligands and Antiferromagnetic Coupling." Inorg. Chem. 2008, 47, 10037-10045. DOI: 10.1021/ic801277r

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34) Arumugam, K.; Yu, R.; Villgrán, D.; Gray, T. G.; Mague, J. T.; Donahue, J. P. "A Convergent Approach to the Synthesis of Multimetallic Dithiolene Complexes." Inorg. Chem. 2008, 47, 5570-5572. DOI: 10.1021/ic800880s

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33) Donahue, J. P.; Murillo, C. A. "An Unusual Trigonal D3 Assembly Composed of Molybdate Anions and Multiply Bonded Dimolybdenum Units." Dalton Trans. 2008, 1547-1551. DOI: 10.1039/b714814c

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32) Yu, R.; Arumugam, K.; Manepalli, A.; Tran, Y.; Schmehl, R.; Jacobsen, H.; Donahue, J. P. "Reversible, Electrochemically Controlled Binding of Phosphine to Iron and Cobalt Bis(dithiolene) Complexes." Inorg. Chem. 2007, 46, 5131-5133. DOI: 10.1021/ic0624569

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31) Arumugam, K.; Bollinger, J.; Fink, M.; Donahue, J. P. "Preparation and Isolation of Dithiolene Thiophosphoryl Molecules as Stable, Protected Forms of Dithiolene Ligands." Inorg. Chem. 2007, 46, 3283-3288. DOI: 10.1021/ic0700203

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30) Zhang, Y.; Donahue, J. P.; Li, C.-J. "Gold(III)-Catalyzed Double Hydroamination of o-Alkynylaniline with Terminal Alkynes Leading to N-Vinylindoles." Org. Lett. 2007, 9, 627-630. DOI: 10.1021/ol062918m

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29) Donahue, J. P.; Jacobsen, H. "Expanding the Scope of the Newman-Kwart Rearrangement. A Computational Assessment." Can. J. Chem. 2006, 84, 1567-1574. DOI: 10.1139/V06-161

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28) Donahue, J. P. "Thermodynamic Scales for Sulfur Atom Transfer and Oxo-for-Sulfido Exchange Reactions." Chem. Rev. 2006, 106, 4747-4783. DOI: 10.1021/cr050044w.

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27) Donahue, J. P. "A Closer Look at the Hydroiodination of Propiolic Acid." Synth. Commun. 2006, 36, 3461-3471. DOI: 10.1080/00397910600942826

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26) Cotton, F. A.; Donahue, J. P.; Gruhn, N. E.; Lichtenberger, D. L.; Murillo, C. A.; Van Dorn, L. O.; Villagrán, D.; Wang, X. "Facilitating Access to the Most Easily Ionized Molecule: A Key Intermediate and Related Compounds." Inorg. Chem. 2006, 45, 201-213. DOI: 10.1021/ic0515709

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25) Cotton, F. A.; Donahue, J. P.; Huang, P.; Murillo, C. A.; Villagrán, D. Z. "Strong Electronic Coupling between Mo2n+ Units: The Oxidation Products of [Mo2(DAniF)3]2(μ-H)2 and Mo2(DAniF)4." Anorg. Allg. Chem. 2005, 631, 2606-2612. DOI: 10.1002/zaac.200500135

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24) Cotton, F. A.; Donahue, J. P.; Lichtenberger, D. L.; Murillo, C. A.; Villagrán, D. "Expeditious Access to the Most Easily Ionized Closed-Shell Molecule, W2(hpp)4." J. Am. Chem. Soc. 2005, 125, 10808-10809. DOI: 10.1021/ja0535458

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23) Medina, I.; Mague, J. T.; Donahue, J. P.; Fink, M. J. "Bis(triphenylsilyl)selenide." Acta Crystallogr., Sect. E. 2005, 61, o2687-o2688. DOI:10.1107/S1600536805023275

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22) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Yu, R. "Synthesis and Structural Characterization of the Molecular Loop [cis-Mo2(N,N'-di-p-anisylformamidinate)2]2(O2C–CH=C=CH–CO2)2." Inorg. Chim. Acta 2005, 358, 1373-1376. DOI:10.1016/j.ica.2004.05.018

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21) Cotton, F. A.; Donahue, J. P.; Hall, M. B.; Murillo, C. A.; Villagrán, D. "Reaction Products of W(CO)6 with Formamidines; Electronic Structure of a W2(µ-CO)2 Core with Unsymmetric Bridging Carbonyls." Inorg. Chem. 2004, 43, 6954-6964. DOI: 10.1021/ic049116c

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20) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "An Asymmetric Edge-Sharing Bioctahedral Complex: (η2-DAniF)MoIII(μ-DAniF)2(μ-O,Cl)MoVCl2 (DAniF = N,N´-di-p-anisylformamidinate)." J. Cluster Sci. 2003, 14, 289-298. DOI: 10.1023/B:JOCL.0000005064.24600.b0

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19) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Pérez, L. M.; Yu, R. "Cyclic Polyamidato Dianions as Bridges between Mo24+ Units: Synthesis, Crystal Structures, Electrochemistry, Absorption Spectra, and Electronic Structures." J. Am. Chem. Soc. 2003, 125, 8900-8910. DOI: 10.1021/ja0358044

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18) Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Pérez, L. M. "Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers: Absorption Spectra and Electronic Structures." J. Am. Chem. Soc. 2003, 125, 5486-5492. DOI: 10.1021/ja0343555

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17) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "Polyunsaturated Dicarboxylate Tethers Connecting Dimolybdenum Redox and Chromophoric Centers: Synthesis, Structures, and Electrochemistry." J. Am. Chem. Soc. 2003, 125, 5436-5450. DOI: 10.1021/ja029101i

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16) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A.; Rockwell, J. "A Molecular Pair Having Two Quadruply Bonded Dimolybdenum Units Linked by a Terephthalate Dianion." Acta Crystallogr., Sect. E 2002, 58, m298-m300. DOI: 10.1107/S160053680200884X

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15) Cotton, F. A.; Daniels, L. M.; Donahue, J. P.; Liu, C. Y.; Murillo, C. A. "The First Designed Syntheses of Bis-Dimetal Molecules in Which the Bridges are Diamidate Ligands." Inorg. Chem. 2002, 41, 1354-1356. DOI: 10.1021/ic025503f

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14) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "The First Supramolecular Assemblies Comprised of Dimetal Units and Chiral Dicarboxylates." Inorg. Chem. Commun. 2002, 5, 59-63. DOI: 10.1016/S1387-7003(01)00345-8

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13) Cotton, F. A.; Donahue, J. P.; Murillo, C. A. "Quadridentate Bridging EO42- (E = S, Mo, W) Ligands and Their Role as Electronic Bridges." Inorg. Chem. 2001, 40, 2229-2233. DOI: 10.1021/ic0012470

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12) Cotton, F. A.; Donahue, J. P.; Lin, C.; Murillo, C. A. "The Simplest Supramolecular Complexes Containing Pairs of Mo2(formamidinate)3 Units Linked with Various Dicarboxylates: Preparative Methods, Structures, and Electrochemistry." Inorg. Chem. 2001, 40, 1234-1244. DOI: 10.1021/ic000934o

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11) Clérac, R.; Cotton, F. A.; Donahue, J. P.; Murillo, C. A.; Timmons, D. J. "Completion of the Series of M2(hpp)4Cl2 Compounds from W to Pt: The W, Os, and Pt Compounds." Inorg. Chem. 2000, 39, 2581-2584. DOI: 10.1021/ic991370v

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10) Lim, B. S.; Donahue, J. P.; Holm, R. H. "Synthesis and Structures of Bis(dithiolene)molybdenum Complexes Related to the Active Sites of the DMSO Reductase Enzyme Family." Inorg. Chem. 2000, 39, 263-273. DOI: 10.1021/ic9908672

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9) Musgrave, K. B.; Donahue, J. P.; Lorber, C.; Holm, R. H.; Hedman, B.; Hodgson, K. O. "An X-ray Spectroscopic Investigation of Bis(dithiolene)molybdenum(IV,V,VI) and –tungsten(IV,V,

VI) Complexes: Symmetrized Structural Representations of the Active Sites of Molybdoenzymes in the DMSO Reductase Family and of Tungstoenzymes in the AOR and F(M)DH Families." J. Am. Chem. Soc. 1999, 121, 10297-10307. DOI: 10.1021/ja990753p

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8) Thapper, A.; Donahue, J. P.; Musgrave, K. B.; Willer, M. W.; Nordlander, E.; Hedman, B.; Hodgson, K. O.; Holm, R. H. "The Unperturbed Oxo-Sulfido Functional Group cis-MoVIOS, Related to That in the Xanthine Oxidase Family of Molybdoenzymes: Synthesis, Structural Characterization, and Reactivity Aspects." Inorg. Chem. 1999, 38, 4104-4114. DOI: 10.1021/ic990440v

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7) Donahue, J. P.; Goldsmith, C. R.; Nadiminti, U.; Holm, R. H. "Synthesis, Structures, and Reactivity of Bis(dithiolene)molybdenum(IV,VI) Complexes Related to the Active Sites of Molybdoenzymes." J. Am. Chem. Soc. 1998, 120, 12869-12881. DOI: 10.1021/ja982914f

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6) Lorber, C.; Donahue, J. P.; Goddard, C. A.; Nordlander, E.; Holm, R. H. "Synthesis, Structures, and Oxo Transfer Reactivity of Bis(dithiolene)tungsten(IV,VI) Complexes Related to the Active Sites of Tungstoenzymes." J. Am. Chem. Soc. 1998, 120, 8102-8112. DOI: 10.1021/ja981015o

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5) Donahue, J. P.; Holm, R. H. "3,4-Bis(1-adamantyl)-1,2-dithiete: the First Structurally Characterized Dithiete Unsupported by a Ring or a Benzenoid Frame." Acta Crystallogr., Sect. C 1998, 54, 1175-1178.  DOI: 10.1107/S0108270198002935

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4) Donahue, J. P.; Lorber, C.; Nordlander, E.; Holm, R. H. "Molybdenum and Tungsten Structural Analogues of the Active Sites of the MoIV + [O] → MoVIO Oxygen Atom Transfer Couple of DMSO Reductases." J. Am. Chem. Soc. 1998, 120, 3259-3260. DOI: 10.1021/ja973917f

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3) Tucci, G. C.; Donahue, J. P.; Holm, R. H. "Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and –tungsten Complexes." Inorg. Chem. 1998, 37, 1602-1608. DOI: 10.1021/ic971426q

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2) Tian, Z.-Q.; Donahue, J. P.; Holm, R. H. "Synthesis of New Types of Dithiolene Ligands." Inorg. Chem. 1995, 34, 5567-5572. DOI: 10.1021/ic00126a029

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1) Holm, R. H.; Donahue, J. P. "A Thermodynamic Scale for Oxygen Atom Transfer Reactions." Polyhedron 1993, 12, 571-589. DOI: 10.1016/S0277-5387(00)84972-4

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